High-efficiency thermoelectric Ba8Cu14Ge6P26: bridging the gap between tetrel-based and tetrel-free clathrates† †Electronic supplementary information (ESI) available: Calculated and experimental powder XRD patterns; tables with crystallographic information; SEM and EDS results; additional DSC, thermal conductivities, and ZT figures. CCDC 1568106. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03482b

A complex stereochemical relay approach to the antimalarial alkaloid ocimicide A1. Evidence for a structural revision† †Electronic supplementary information (ESI) available: Supplementary schemes, figures, and tables, general experimental remarks, synthetic procedures, catalogues of experimental and calculated nuclear magnetic resonance spectra. CCDC 1536046. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01127j Click here for additional data file. Click here for additional data file.

Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [FeIII(acac2-trien)]+ and [FeIII(sal2-trien)]+ molecules† †Electronic supplementary information (ESI) available: Experimental section, structural views of 1, 2 and 3, powder X-ray diffraction patterns of 1, 2 and 3, isothermal magnetization of 1, 2 and 3 at 2 K, AC susceptibility measurements of 3, DLS, EDS analysis, optical microscopy, SEM, TEM and AFM images of flakes of 2 and 4. CCDC 1054372–1054374. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00957j Click here for additional data file. Click here for additional data file.

Instituto de Ciencia Molecular, Universidad Paterna, 46980, Spain. E-mail: miguel.cle Fax: +34 963543273; Tel: +34 963544405 † Electronic supplementary information structural views of 1, 2 and 3, powder X isothermal magnetization of 1, 2 and 3 a of 3, DLS, EDS analysis, optical micros akes of 2 and 4. CCDC 1054372–105437 CIF or other electronic format see DOI: 10 Cite this: Chem. Sci., 2015, 6...

Solvent modified spin crossover in an iron(iii) complex: phase changes and an exceptionally wide hysteresis† †Electronic supplementary information (ESI) available: Crystallographic details, structural figures, VT-PXRD data and figures, Mössbauer spectroscopic data, DSC and TGA results. CCDC 1519938–1519948. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc05317c Click here for additional data file. Click here for additional data file.

Halogen bonded Borromean networks by design: topology invariance and metric tuning in a library of multi-component systems† †Electronic supplementary information (ESI) available: Materials and methods, NMR, DSC, powder and single crystal X-ray data. CCDC 1505909–1505934. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc04478f Click here for additional data file. Click here for additional data file. Click here for additional data file.

Laboratory of Nanostructured Fluorinate Chemistry, Materials, and Chemical Eng Milano, Via L. Mancinelli 7, 20131 Milano, VTT-Technical Research Centre of Finland, † Electronic supplementary information ( NMR, DSC, powder and single crystal XESI and crystallographic data in CIF 10.1039/c6sc04478f ‡ Present address: Laboratory of Nanomaterials, Université Libre de Bru Bruxelles, Belgium. Cite th...

Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysis† †Electronic supplementary information (ESI) available: Experimental details, spectral data, and crystallographic results. CCDC 1533276 and 1533274. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01703k Click here for additional data file. Click here for additional data file.